| Unlockable: | How to Unlock: |
| Unlock Character: Brago & Sherry | Beat them in the Story mode |
| Unlock Character: Kanchome & Folgore | Beat them in the Story mode |
| Unlock Character: Kolulu & Lori | Beat them in the Story mode |
| Unlock Character: Rops & Apolo | Beat them in the Story mode |
| Unlock Character: Tia & Megumi | Beat them in the Story mode |
| Unlock mode: Mini-game "Create a Volcan!!" | Complete the game once |
| Unlock mode: VS Challenge | Complete the game once |
| Unlock mode: VS Survival | Complete the game once |
| Unlockable: | How to Unlock: |
| #10 Volunlun | Beat "Create a Volcan" on difficult mode using the bottom route |
| #11 Kanchome's Snacks | Beat Challenge Mode on Normal with Ponygon & Raiku Sensei |
| #12 Folgore's Skateboard | Beat 00F ~Iron Folgore~ on difficult mode |
| #13 Folgore's CD | Beat Challenge Mode with Folgore/Kanchomé |
| #14 Tia's watch | Beat Challenge Mode with Megumi/Tia |
| #15 Ponygon's toy | Unlock Zeno & Dufort.Then beat Challenge Mode on Normal with Zeno & Dufort |
| #16 Princess Pear | Beat "Create a Volcan" on difficult mode switching off between top and bottom route |
| #17 Praying Mantis Joe Figure | Beat "Create a Volcan" on difficult mode using two bottom and one top route or two top and one bottom |
| #18 Kanchome's paddle board | Beat Challenge Mode on Normal with Brago & Berserk Sherry (blue) |
| #19 Yellowtail | Beat Challenge Mode on Normal with Wonrei & Li-en |
| #20 Rushka's Sheep | Beat Story mode on Normal without loosing. |
| #7 Delighted Grapefruit | Beat the mini game in story mode after beating the story twice without continuing |
| Crybaby Tangerine (item 6) | Beat the mini-game that appears after the second battle of the story mode for the first time |
| Evil Flower (item 21) | Beat part 5 of the story mode |
| Naomi's Car (item 9) | Beat "Naomi Attack!!" on difficult mode |
| Smiley-Face Orange (item 7) | Beat the mini-game that appears after the second battle of the story mode for the second time |
| Tina (item 5) | Beat "Create a Volcan!!" on difficult mode |
| Tina No.5 | Play ''Create a Vulcan'' Minigame on difficult |
| Volcan (Doctor Version) (item 3) | Beat "Create a Volcan!!" on normal mode |
| Volcan (Mountain Version) (item 2) | Beat "Create a Volcan!!" on easy mode |
| Volcan 300 (item 1) | Complete the story mode once |
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