Beat Saints In Story Mode .Beat Saint Legend Mode With Surplies Characters And Won 20 battles In Eter nal Battle Mode To Unlock Them.
| Unlockable: | How to Unlock: |
| (Surplies)Aphrodite | Beat Mepisto As Mu In Story Mode. |
| (Surplies)Camus | Beat Mepisto As Mu In Story Mode. |
| (Surplies)Mepisto | Beat Mepisto As Seiya In Story Mode. |
| (Surplies)Saga | Beat Mepisto As Mu In Story Mode. |
| (Surplies)Shura | Beat Mepisto As Mu In Story Mode. |
| Aiacos | Procceed Aiacos In The Hades Mode. |
| Aiolia | Proceed Him In Story Mode. |
| Aiolos | Beat 30 battles In Eternal Battle Mode. |
| Aldebaran | Proceed Him In Story Mode. |
| Aqurius Hyoga | Beat Aqurius Hyoga In Saint Legend Mode. |
| Dohko | Proceed Him In Story Mode. |
| Final Cloth Hyoga | Beat Rhadamanthys As Seiya In The Hades Mode. |
| Final Cloth Ikki | Beat Rhadamanthys As Seiya In The Hades Mode. |
| Final Cloth Seiya | Beat Rhadamanthys As Seiya In The Hades Mode. |
| Final Cloth Shiryu | Beat Rhadamanthys As Seiya In The Hades Mode. |
| Final Cloth Shun | Beat Rhadamanthys As Seiya In The Hades Mode. |
| First Cloth Seiya | Won Lighttining Battle Mode As Seiya At Least 5 or 6 Minutes. |
| First Cloth Shiryu | Won Lighttining Battle Mode As Seiya At Least 5 or 6 Minutes. |
| Geminisaint | Proceed Him In Story Mode. |
| Gold Aphrodite | Beat Saint Legend Mode As (Surplies) Aphrodite. |
| Gold Camus | Beat Saint Legend Mode As (Surplies) Camus. |
| Gold Cloth Hyoga | Complete Saint Legend Mode with Hyoga |
| Gold Cloth Ikki | Complete Saint Legend Mode with Ikki |
| Gold Cloth Seiya | Complete Saint Legend Mode with Seiya |
| Gold Cloth Shion | After unlocking Shion just press triangle (default controls) when selecting him. |
| Gold Cloth Shiryu | Complete Saint Legend Mode with Shiryu |
| Gold Cloth Shun | Complete Saint Legend Mode with Shun |
| Gold Mepisto | Beat Saint Legend Mode As (Surplies)Mepisto. |
| Gold Saga | Beat Saint Legend Mode As (Surplies)Saga. |
| Gold Shura | Beat Saint Legend Mode As (Surplies) Shura. |
| Hyoga (First Cloth) | beat lightning battle in 8 minutes or less. |
| Ikki (First Cloth) | beat lightning battle in 6 minutes or less. |
| Libra Shiryu | Beat Libra Shiryu In Saint Legend Mode. |
| Marin | Won 10 Battles In Eternal Battle Mode. |
| Milo | Proceed Him In Story Mode. |
| Minos | Procceed Minos In The Hades Mode. |
| Mu | Proceed Him In Story Mode. |
| Orpheus | Beat Orpheus As Seiya In The Hades Mode. |
| Rhadamanthys | Beat Radamanthys As Mu In The Hades Mode. |
| Sagittarius Seiya | Beat Sagittarius Seiya In Saint Legend Mode. |
| Saint Cloth Myth | Beat the legend mode (Example: if you beat the legend mode with shaka you unlock the virgo cloth) |
| Seiya (First Cloth) | beat lightning battle in 10 minutes or less. |
| Shaina | Won 20 Battles In Eternal Battle Mode. |
| Shaka | Proceed Him In Story Mode. |
| Shion | Beat Shion As Shiryu In The Hades Mode. |
| Shiryu (First Cloth) | beat lightning battle in 9 minutes or less. |
| Shun (First Cloth) | beat lightning battle in 7 minutes or less. |
| Unlock First Cloth Hyoga | Have a Saint Seiya: Chapter Sanctuary save into the Memory Card |
| Unlock First Cloth Ikki | Have a Saint Seiya: Chapter Sanctuary save into the Memory Card |
| Unlock First Cloth Seiya | Have a Saint Seiya: Chapter Sanctuary save into the Memory Card |
| Unlock First Cloth Shiryu | Have a Saint Seiya: Chapter Sanctuary save into the Memory Card |
| Unlock First Cloth Shun | Have a Saint Seiya: Chapter Sanctuary save into the Memory Card |
Complete 10 rounds in Eternal Battle Mode with each character to view their 3D character model in Zodiac History Mode
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Saint Seiya: The Hades Items
