Unlockable characters...
| Unlockable: | How to Unlock: |
| Cao Cao | Clear Musou Mode with 3 Wei characters |
| Cao Pi | Deafeat Cao Pi within 5 minutes on Wu side of He Fei |
| Cao Ren | Succeed in Battle Objective 2 on the Lu Bu side of Fan Castle |
| Diao Chan | Clear Musou Mode with 1 character from each Kingdom |
| Dong Zhuo | Clear Musou Mode with Lu Bu |
| Gan Ning | Clear Musou Mode with 1 Wu character |
| Guan Ping | Succeed in 2 battle objectives on the Shu side of Fan Castle and finish battle with Guan Ping alive |
| Huang Gai | Succeed in Battle Objective 3 on the Wu side of The Battle of Chi Bi |
| Huang Zhong | Succeed in 1 battle objective on the Wei side of Ding Jun Mountain |
| Liu Bei | Clear Musou Mode with 3 Shu characters |
| Lu Bu | Clear Musou Mode with Liu Bei, Cao Cao, and Sun Jian |
| Lu Meng | Succeed in 2 battle objectives on the Wei side of He Fei |
| Ma Chao | Succeed in 2 battle objectives on the Wei side of Han Zhong Attack Defense Battle |
| Pang Tong | Succeed in 3 battle objectives at Cheng Du battle and finish battle with Pang Tong alive |
| Sun Ce | Succeed in Battle Objective 1 on the Sun Jian side of the Battle of Xia Pi |
| Sun Jian | Clear Musou Mode with 3 Wu characters |
| Sun Quan | Succeed in Battle Objective 1 on the Lu Bu side of The Battle of Chi Bi |
| Wei Yan | Succeed in 2 battle objectives on the Shu side of WuZhang Plains and finish battle with Wei Yan alive |
| Xiahou Yuan | Succeed in 1 battle objective on the Shu side of Ding Jun Mountain |
| Xiao Quio | Succeed in Battle Objective 3 on the Wu side of the Battle of Shi Ting |
| Xu Chu | He Fei, Wu side, Personally kill Cao Ren and Xu Chu |
| Xu Huang | Succeed in 2 battle objectives on the Wei/Wu side of Fan Castle |
| Yuan Shao | As Wei, complete all 3 targets and capture Wu Chao before completing the stage. |
| Yue Ying | Succeed in Battle Objective 1 on the Wei side of the Battle of Wu Zhang Plains |
| Zhang Liao | Clear Musou Mode with 1 Wei character |
| Zheng He | Succeed in 2 battle objectives on the Shu side of Han Zhong Attack Defense Battle |
| Zhou Tai | Succeed in 3 battle objectives on the Shu side of Yi Ling |
| Zhuge Liang | Clear Musou Mode with 1 Shu character |
Clear Musou Mode with 1 character from Wu, Shu, Wei, and Other.
Clear Musou Mode with any 1 character.
Beat any musou mode on Easy or Normal.
Beat Wei, Wu, Shu, and Other musou mode.
Each character has an alternate costume. You can unlock it by getting them to level 25. This is for every character.
Complete the following achievements to unlock Xbox Live Gamerscore points.
| Unlockable: | How to Unlock: |
| 1st in Gauntlet (10 pts) | Rank 1st (Pesonal Best points) In Gauntlet. |
| 1st in Havoc (10 pts) | Rank 1st (Personal Best points) In Havoc. |
| 1st in Rampage (10 pts) | Rank 1st (Personal Best points) In Rampage. |
| 1st in Speed RUN (10 pts) | Rank 1st (Personal Best points) in Speed Run. |
| 1st in Sudden Death (10 pts) | Rank 1st (Personal Best points) in Sudden Death. |
| Musou Mode Master (50 pts) | All Musou modes cleared. |
| Scenario Captain (40 pts) | 30 or more scenarios cleared. |
| Scenario Corporal (30 pts) | 20 or More Scenarios Cleared. |
| Scenario General (50 pts) | All scenarios cleared. |
| Scenario Private (20 pts) | 10 or more scenarios cleared. |
| Target Captain (50 pts) | 100 or more Targets achieved. |
| Target Corporal (40 pts) | 70 or more Targets achieved. |
| Target General (60 pts) | All Targets achieved. |
| Target Private (30 pts) | 50 or more targets achieved. |
| The Arm of Cao Cao (10 pts) | Xiahou Yuan has been unlocked. |
| The Barbarian Lord (10 pts) | Wei Yan has been unlocked. |
| The Beautiful Dancer (30 pts) | Diao Chan has been unlocked. |
| The Courageous Lord (10 pts) | Xu Huang has been unlocked. |
| The Ferocious Warrior (10 pts) | Taishi Ci has been unlocked. |
| The Fledgling Phoenix (10 pts) | Pang Tong has been unlocked. |
| The Forthright Lord (30 pts) | Zhang Liao has been unlocked. |
| The General of Heaven (10 pts) | Zhang Jiao has been unlocked. |
| The Little Conqueror(10 pts) | Unlock Sun Ce. |
| The Lord Of Beauty (10 pts) | Zhang He has been unlocked. |
| The Loyal Warrior (10 pts) | Zhou Tai has been unlocked. |
| The Master General (10 pts) | Lu Meng has been unlocked. |
| The Patriarch of Yuan (10 pts) | Yuan Shao has been unlocked. |
| The Patriarch of Yuan (10 pts) | Yuan Shao has been unlocked. |
| The Reckless Pirate (30 pts) | Gan Ning has been unlocked. |
| The Sleeping Dragon (30 pts) | Zhuge Liang has been unlocked. |
| The Son Of Guan Yu (10 pts) | Guan Ping has been unlocked. |
| The Splendid One (10 pts) | Ma Chao has been unlocked. |
| The Tiger General (10 pts) | Huang Zhong has been unlocked. |
| The Tiger of Jiang Dong(10 pts) | Unlock Sun Jian. |
| The Veteran General (10 pts) | Huang Gai has been unlocked. |
| The Wise Lady (10 pts) | Yue Ying has been unlocked. |
Raise up any character's experience to LV. 50. A Voice Gallery will be unlocked for that character in the Camp.
Successfully complete Musou mode to unlock the Movie Player.
Shin Sangoku Musou 5 
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